********************************************************************** *** Atmospheric CO concentrations (ppbv) derived from flask *** *** samples collected at Shetland Islands, Scotland *** *** Source: L.P. Steele *** *** P.B. Krummel *** *** R.L. Langenfelds *** *** Commonwealth Scientific, *** *** and Industrial Research Organisation, *** *** Aspendale, Victoria, *** *** Australia 3195 *** *** *** *** February 2003 *** *** *** ********************************************************************** Year Jan. Feb. Mar. Apr. May Jun. Jul. Aug. Sep. Oct. Nov. Dec. Ann. Ave. 1992 136.55 1993 144.48 153.83 162.43 162.05 136.83 104.28 90.67 87.98 98.39 117.74 129.26 148.18 128.01 1994 163.8 163.89 172.36 167.41 139.31 111.51 96.16 104.87 119.84 127.17 132.43 142 136.73 1995 157.04 162.43 163.82 162.48 138.86 113.72 105 96.96 102.85 117.42 121.87 134.29 131.40 1996 154.74 160.27 159.59 153.44 133.91 115.75 101.29 94.5 105.02 119.94 128.26 141.47 130.68 1997 153.91 154.62 155.98 155.11 136.64 107.33 87.51 82.52 91.83 112.62 135.19 147.31 126.71 1998 155.54 159.57 164.38 166.68 146.74 117 104.48 119.88 151.79 171 159.67 155.97 147.73 1999 165.74 159.09 154.72 156.06 138.27 112.01 90.56 84.93 96.66 104.96 113.28 126.93 125.27 2000 136.36 140.99 147.11 144.51 126.84 103.29 86.05 88.2 95.3 96.36 106.57 124.59 116.35 2001 135.6 144.77 153.65 149.81 128.65 103.62 89.76 84.96 91.96 106.29 114.22 125.34 119.05 Monthly values, expressed in parts per billion by volume (ppbv), are linked to the gravimetrically derived scale of NOAA/CMDL using a single high-pressure cylinder standard with a CO mole fraction of 196 ppbv. Stability of the CSIRO scale and variations in instrument response are monitored with about 20 high pressure cylinder standards, with lifetimes of 4 to 10 or more years, spanning a CO range of 20 to 400 ppbv. Monthly values are calculated as the mean of the daily values from a smooth curve fit to the data using curve-fitting routines described by Thoning et al. 1989. Annual values are the arithmetic means of the 12 monthly values.