CO2 Flux Estimated from Air-Sea Difference in CO2 Partial Pressure (Revised October 2009)

The files in this site contain a revised (October 2009) version of the climatological mean values in 4° Latitude X 5° Longitude box areas and the distribution maps. These were originally published in: Takahashi, et al. (2009), DSR II, 56, 554-577.

The data file containing annual flux data for each 4° X 5° box is located here.

The data file from which this map was created, including all 12 months of data is here. This data file, in ASCII form, also contains the flux data and the intermediate values used to calculate that flux for each month.

In December 2010 our colleague, R. Wanninkhof pointed out a problem with the flux data for the month of December. The file of ice coverage for December was corrupted and showed zero ice for the entire month, worldwide. This has been corrected with the estimated percent of ice and the flux recalculated. Version "c" of the data files contain this correction.

In June 2009 we discovered and fixed a small programming bug in the interpolation scheme affecting data between the prime meridian and 2.5°E Longitude. The explanation is here.

In October 2009 our colleague N. Metzl pointed out a problem with an Indian Ocean data set. We have corrected that database and rerun the interpolation scheme. The master files have been updated, and a detailed explanation with descriptive maps is located here.

Our earlier effort, published in DEEP SEA RESEARCH PART II, Vol 49, 2002, pp 1601-1622 for reference year 1995, (as corrected) is preserved here.


 
Maps of (1) pCO2 at Sea Surface Temperature,
 
(2) Sea-Air pCO2 Difference,
 
(3) Sea-Air CO2 Flux, as a rate per unit area,
 
(4) Total Sea-Air CO2 flux from each 4°x5° Box.

To test our interpolation scheme we used Sea Surface Temperature (SST) in place of pCO2 as the interpolated parameter. We compared this output to the climatological SST from the NOAA Objective Interpolation data (Shea, et al.1992). The results of that comparison are summarized here.

A climatological mean distribution for the surface water pCO2 over the global oceans in non-El Niño conditions are presented with spatial resolution of 4° (latitude) x 5° (longitude) for a reference year 2000 based upon about 3 million measurements of surface water pCO2 obtained from 1970 to 2007 (Takahashi et al., 2009). The database used for this study is archived at the Carbon Dioxide Information and Analysis Center (CDIAC), Oak Ridge, National Laboratory, (Version 1.0, Takahashi et al., 2008), and is about 3 times larger than the 0.94 million used for our earlier paper (Takahashi et al., 2002). A time-trend analysis using deseasonalized surface water pCO2 data in portions of the North Atlantic, North and South Pacific and Southern Oceans (which cover about 27% of the global ocean areas) indicates that the surface water pCO2 over these oceanic areas has increased on average at a mean rate of 1.5 µatm/yr with basin-specific rates varying between 1.2 ± 0.5 and 2.1 ± 0.4 µatm/yr. A global ocean database for a single reference year 2000 is assembled using this mean rate for correcting observations made in different years to the reference year. Although it cannot be thoroughly documented due to the limited extent of observations, seasonal changes in pCO2 in the Southern Ocean are approximated by using the data for under-ice waters during austral winter and those for the marginal ice and ice-free zones. The observations made during El Niño periods in the equatorial Pacific and those made in coastal zones are excluded from the database.

The net air-sea CO2 flux is estimated using the sea-air pCO2 difference and the air-sea gas transfer rate that is parameterized as a function of (wind speed)2 with a scaling factor of 0.26. This is estimated by inverting the bomb Carbon-14 data using Ocean General Circulation models and the 1979-2005 NCEP-DOE AMIP-II Reanalysis (R-2) wind speed data. The equatorial Pacific (14°N-14°S) is the major source for atmospheric CO2, emitting about +0.48 Pg-C/yr, and the temperate oceans between 14° and 50° in the both hemispheres are the major sink zones with an uptake flux of -0.70 Pg-C/yr for the northern and –1.05 Pg-C/yr for the southern zone. The high latitude North Atlantic, including the Nordic Seas and portion of the Arctic Sea, is the most intense CO2 sink area on the basis of per unit area, with a mean of –2.5 tons-C / month / km2 (1 Ton = 106 grams). This is due to the combination of the low pCO2 in seawater and high gas exchange rates. In the ice-free zone of the Southern Ocean (50°S-62°S), the mean annual flux is small (-0.06 Pg-C/yr) because of a cancellation of the summer uptake CO2 flux with the winter release of CO2 caused by deepwater upwelling. The annual mean for the contemporary net CO2 uptake flux over the global oceans is estimated to be -1.4 ± 0.7 Pg-C/yr. Taking the pre-industrial steady state ocean source of 0.4 ± 0.2 Pg-C/yr into account, the total ocean uptake flux including the anthropogenic CO2 is estimated to be –2.0 ± 0.7 Pg-C/yr in 2000.

Please site this data set as:

Takahashi, T., Sutherland, S. C., Wanninkhof, R., Sweeney, C., Feely, R. A., Chipman, D. W., Hales, B., Friederich, G., Chavez, F., Watson, A., Bakker, D. C. E., Schuster, U., Metzl, N., Yoshikawa-Inoue, H., Ishii, M., Midorikawa, T., Nojiri, Y., Sabine, C., Olafsson, J., Arnarson, T. S., Tilbrook, B., Johannessen, T., Olsen, A., Bellerby, R., Körtzinger, A., Steinhoff, T., Hoppema, M., de Baar, H. J. W., Wong, C. S., Delille, B. and Bates, N. R. (2009). Climatological mean and decadal changes in surface ocean pCO_2 , and net sea-air CO_2 flux over the global oceans. Deep-Sea Res. II, 554-577. doi: 10.1016/j.dsr2.2008.12.009.

REFERENCES:

  1. Takahashi, T., Sutherland, S. C., Sweeney, C., Poisson, A., Metzl, N., Tillbrook, B., Bates, N., Wanninkhof, R., Feely, R. A., Sabine, C., Olafsson, J. and Nojiri, Y. (2002). Global sea-air CO2 flux based on climatological surface ocean pCO2, and seasonal biological and temperature effects, Deep-Sea Res. II, 49, 1601-1622.
  2. Takahashi, T., Sutherland, S. C. and Kozyr, A. (2008). Global Ocean Surface Water Partial Pressure of CO2 Database: Measurements Performed during 1968-2006 (Version 1.0). ORNL/CDIAC-152, NDP-088. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U. S. Department of Energy, Oak Ridge, TN 37831, pp.20.
  3. Takahashi, T., S. C. Sutherland, R. Wanninkhof, C. Sweeney, R. A. Feely, D. W. Chipman, B. Hales, G. Friederich, F. Chavez, A. Watson, D. C. E. Bakker, U. Schuster, N. Metzl, H. Yoshikawa-Inoue, M. Ishii, T. Midorikawa, Y. Nojiri, C. Sabine, J. Olafsson, Th. S. Arnarson, B. Tilbrook, T. Johannessen, A. Olsen, Richard Bellerby, A. Körtzinger, T. Steinhoff, M. Hoppema, H. J. W. de Baar, C. S. Wong, Bruno Delille and N. R. Bates (2009). Climatological mean and decadal changes in surface ocean pCO2, and net sea-air CO2 flux over the global oceans. Deep-Sea Res. II, 56, 554-577. doi: 10.1016/j.dsr2.2008.12.009.


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