Atmospheric CO₂ From Flask Air Samples at La Jolla Pier, California, U.S.A.

Graphics    Digital Data

C.D. Keeling and T.P. Whorf

Carbon Dioxide Research Group, Scripps Institution of Oceanography, University of California, La Jolla, California 92093-0444, U.S.A.

Period of Record

1968-2001

Methods

Replicate samples of atmospheric CO₂ were collected at intervals of roughly one month, on average over the period of record, although sampling intervals have ranged from weekly to almost quarterly in a few early cases. The sampling has become more frequent and more regular in recent years. Samples are collected in 5-L evacuated glass flasks, and then returned to Scripps Institution of Oceanography (SIO) where CO₂ concentrations have been determined using an Applied Physics Corporation (APC) nondispersive infrared gas analyzer. Further information on measurements, calibration procedures and analysis is available in the references listed below.

La Jolla Pier, California, U.S.A.
32°9' N, 117°3' W
10 m above MSL

Trends

The first full year of complete, unflagged, data was from the continuous data record, 1973, so those data are used here as a baseline. The average CO₂ concentration value during 1973 was 333.0 ppmv; 2001 values averaged 372.5 ppmv, for an upward trend of 1.52 ppmv/year. Graphics here show the first and last complete year of data, to display the change in mean over time and the annual amplitudes. Long term trend curves are better displayed using SIO's monthly averaged data.

References

• Guenther, P.R., A. Bollenbacher, C.D. Keeling, and D. Moss. 2002 Technical Report: Infrared Analyses of NOAA Primary CO₂-in-Air Reference Gas Standards at SIO, 1991-1999.
• Guenther, P.R., G. Emanuele, and C.D. Keeling. 2002. Alternative Formulation of 1985-1999 Calibrations after Re-calibration of 4cc Chanber Volume of Mercury Manometer. Addendium to: Scripps Reference Gas Calibration System for Carbon-Dioxide-in Nitrogen and Carbon Dioxide-in-Air Standards: Revision of 1999, February 2002.
  See Diagram of the constant-volume mercury-column manometer.
• Keeling, C.D., R.B. Bacastow, A.F. Carter, S.C. Piper, T.P. Whorf, M. Heimann, W.G. Mook, and H. Roeloffzen. 1989. A three-dimensional model of atmospheric CO₂ transport based on observed winds: 1. Analysis of observational data. In D.H. Peterson (ed.), Aspects of Climate Variability in the Pacific and the Western Americas, 165-236, Geophysical Monograph 55, American Geophysical Union, Washington, DC.
• Keeling, C.D., T.P. Whorf, M. Wahlen & J. van der Plicht. 1995. Interannual extremes in the rate of rise of atmospheric carbon dioxide since 1980, Nature 375, 666-670.
• Keeling, C.D., S.C. Piper, R.B. Bacastow, M. Wahlen, T.P. Whorf, M. Heimann, and H.A. Meijer. 2001. Exchanges of Atmospheric CO₂ and CO¹³CO₂ with the Terrestrial Biosphere and Oceans from 1978 to 2000. I. Global Aspects. SIO Reference No. 01-06 (Revised from SIO Reference No. 00-21), June 2001.
• Keeling, C.D., P.R. Guenther, G. Emanuele III, A. Bollenbacher, and D.J. Moss. 2002. Scripps Reference Gas Calibration System for Carbon Dioxide-in-Nitrogen and Carbon Dioxide-in-Air Standards: Revision of 1999 (with Appendix and Addendum). SIO Reference Series No. 01-11.
  See Diagram of the constant-volume mercury-column manometer.

10/2004